Geochemistry and the optics of geospatial analysis as a preposition of water quality on a macroscale.

The water treatment depends exclusively on the identification of residues containing toxic chemical elements accumulated in NPs (nanoparticles), and ultrafine particles sourced from waste piles located at old, abandoned sulfuric acid factories containing phosphogypsum requires global attention. The general objective of this study is to quantify and analyze the hazardous chemical elements present in the leachate of waste from deactivated sulfuric acid factories, coupled in NPs and ultrafine particles, in the port region of the city of Imbituba, Santa Catarina, Brazil. Samples were collected in 2020, 2021, and 2022. Corresponding images from the Sentinel-3B OLCI satellite, taken in the same general vicinity, detected the levels of absorption coefficient of Detritus and Gelbstoff (ADG443_NN) in 443 m-1, chlorophyll-a (CHL_NN (m-3)), and total suspended matter (TSM_NN (g m-3) at 72 points on the marine coast of the port region. The results of inductively coupled plasma atomic-emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS) demonstrate that the leaching occurring in waste piles at the port area of Imbituba was the likely source of hazardous chemical elements (e.g., Mg, Sr, Nd, and Pr) in the environment. These leachates were formed due to the presence of coal pyrite and Fe-acid sulfates in said waste piles. The mobility of hazardous chemical elements potentiates changes in the marine ecosystem, in relation to ADG443_NN (m-1), CHL_NN (m-3), and TSM NN (g m-3), with values greater than 20 g m-3 found in 2021 and 2022. This indicated changes in the natural conditions of the marine ecosystem up to 30 km from the coast in the Atlantic Ocean, justifying public initiatives for water treatment on a global scale.

Nanoparticles in terrestrial sediments and the behavior of the spectral optics of Sentinel-3B OLCI Satellite images in a river basin of UNESCO World Cultural and Natural Heritage.

The dangerous chemical elements associated with nanoparticles (NPs) and ultra-fine sediment particles in hydrological bays have the capacity to move contaminants to large oceanic regions. The general objective of this study is to quantify the major chemical elements present in NPs and ultra-fine particles in aquatic sediments sampled from Guanabara Bay and compare these data to values determined through spectral optics using the Sentinel-3B Satellite OLCI (Ocean Land Color Instrument) during the winter and summer seasons of 2018, 2019, 2020, 2021, and 2022. This is done to highlight the impacts anthropogenic environmental hazards have on the marine ecosystem and human beings. Ten aquatic sediment field collection points were selected by triangulated irregular network (TIN). Samples were subjected to analysis by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron dispersion spectroscopy (EDS), and transmission electron microscopy (TEM), which enabled a detailed analysis using scanning transmission electron microscopy (STEM). Geospatial analyses using Sentinel-3B OLCI Satellite images considered Water Full Resolution (WFR) at 300 m resolution, in neural network (NN), normalized at 0.83 µg/mg. A maximum average spectral error of 6.62% was utilized for the identification of the levels of Absorption Coefficient of Detritus and Gelbstoff (ADG443_NN) at 443 m-1, Chlorophyll-a (CHL_NN) (m-3), and Total Suspended Matter (TSM_NN) (g m-3) at 581 sample points. The results showed high levels of ADG443_NN, with average values as high as of 4444 m-1 (summer 2021). When related to the analyses of nanoparticulate sediments and ultrafine particles collected in the field, they showed the presence of major chemical elements such as Ge, As, Cr, and others, highly toxic to human health and the aquatic environment. The application of satellite and terrestrial surveys proved to be efficient, in addition to the possibility of this study being applied to other hydrological systems on a global scale.

Detection of atmospheric aerosols and terrestrial nanoparticles collected in a populous city in southern Brazil.

The main objective of this study is to analyze hazardous elements in nanoparticles (NPs) (smaller than 100 nm) and ultrafine particles (smaller than 1 µm) in Porto Alegre City, southern Brazil using a self-made passive sampler and Sentinel-3B SYN satellite images in 32 collection points. The Aerosol Optical Thickness proportion (T550) identification was conducted using images of the Sentinel-3B SYN satellite at 634 points sampled in 2019, 2020, 2021, and 2022. Focused ion beam scanning electron microscopy analyses were performed to identify chemical elements present in NPs and ultrafine particles, followed by single-stage cascade impactor to be processed by high-resolution transmission electron microscopy. This process was coupled with energy-dispersive X-ray spectroscopy and later analysis via secondary ion mass spectrometry. Data was acquired from Sentinel-3B SYN images, normalized to a standard mean of 0.83 µg/mg, at moderate spatial resolution (260 m), and modeled in the Sentinel Application Platform (SNAP) software v.8.0. Statistical matrix data was generated in the JASP software (Jeffreys's Amazing Statistics Program) v.0.14.1.0 followed by a K-means cluster analysis. The results demonstrate the presence of between 1 and 100 nm particles of the following chemical elements: Si, Al, K, Mg, P, and Ti. Many people go through these areas daily and may inhale or absorb these elements that can harm human health. In the Sentinel-3B SYN satellite images, the sum of squares in cluster 6 is 168,265 and in cluster 7 a total of 21,583. The use of images from the Sentinel-3B SYN satellite to obtain T550 levels is of great importance as it reveals that atmospheric pollution can move through air currents contaminating large areas on a global scale.

Nanoparticles containing hazardous elements and the spatial optics of the Sentinel-3B OLCI satellite in Amazonian rivers: a potential tool to understand environmental impacts.

The Amazon River is the longest river in the world. The Tapajós River is a tributary to the Amazon. At their junction, a marked decrease in water quality is evident from negative impacts from the constant activity of clandestine gold mining in the Tapajós River watershed. The accumulation of hazardous elements (HEs), capable of compromising environmental quality across large regions is evident in the waters of the Tapajós. Sentinel-3B OLCI (Ocean Land Color Instrument) Level-2 satellite imagery with Water Full Resolution (WFR) of 300 m was utilized to detect the highest potential for the absorption coefficient of detritus and gelbstoff in 443 m-1 (ADG443_NN), chlorophyll-a (CHL_NN) and total suspended matter concentration (TSM_NN), at 25 points in the Amazon and Tapajós rivers (in 2019 and 2021). Physical samples of riverbed sediment collected in the field at the same locations were analyzed for NPs and ultra-fine particles to verify the geospatial findings. The riverbed sediment samples collected in the field were studied by Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), with selected area electron diffraction (SAED), following laboratory analytical procedures. The Sentinel-3B OLCI images, based on the Neural Network (NN) were calibrated by the European Space Agency (ESA), with a standard average normalization of 0.83 µg/mg, containing a maximum error of 6.62% applied to the sampled points. The analysis of the riverbed sediment samples revealed the presence of the following hazardous elements: As, Hg, La, Ce, Th, Pb, Pd, among several others. The Amazon River has significant potential to transport ADG443_NN (55.475 m-1) and TSM_NN (70.787 gm-3) in sediments, with the possibility of negatively impacting marine biodiversity, in addition to being harmful to human health over very large regions.

Hazardous elements in urban cemeteries and possible architectural design solutions for a more sustainable environment.

The general objective of this study is to identify the presence of hazardous elements in the soils of five urban cemeteries in the city of Passo Fundo, in southern Brazil, and to design solutions (architecturally) for future cemeteries to be more sustainable by mitigating toxicological risks to the population residing in the area. A total of 250 soil samples were obtained from points within the cemeteries and in areas surrounding the two oldest cemeteries at a distance of up to 400 m. Twelve architects who design cemeteries primarily focused on sustainability were interviewed, and presented their suggestions for sustainable urban cemetery design. The Building Information Modeling (BIM) computer modeling system was utilized to present a visual representation of suggested architectural features by these architects. The concentration of Pb in the vicinity of cemeteries deserves special attention, as concentrations of this neurotoxin exceed the federal limits set by Brazil. Soil Pb values were found to exceed the limit of 72 mg kg-1 up to a distance of 400 m from the walls of cemeteries A and B, indicating the presence of a danger to human health even at greater distances. This manuscript highlights construction features that enable future burial structures to adequately mitigate the very real problem of contaminants entering the environment from current cemetery design. Two-thirds of the technicians interviewed for this manuscript, each of whom specialize in Brazilian cemetery design, highlighted the importance of revitalizing urban vegetation both when constructing and revitalizing urban vertical cemeteries.

Terrestrial nanoparticle contaminants and geospatial optics using the Sentinel-3B OLCI satellite in the Tinto River estuary region of the Iberian Peninsula.

The Tinto River is known globally for having a reddish color due to the high concentration of dissolved metals in its waters. The general objective of this study is to analyze the dispersion of nanoparticles (NPs) and ultra-fine particles in terrestrial and geospatial suspended sediments (SSs) using Sentinel-3B OLCI (Ocean Land Color Instrument) satellite images; by examining water turbidity levels (TSM_NN), suspended pollution potential (ADG_443_NN) and presence of chlorophyll-a (CHL_NN). The images were collected in the estuary of the Tinto River, in the city of Nerva, Spanish province of Huelva, between 2019 and 2021. The following hazardous elements were identified in nanoparticles and ultra-fine particles by FE-SEM/EDS: As, Cd, Ni, V, Se, Mo, Pb, Sb and Sn. Sentinel-3B OLCI satellite images detected a 2019 TSM_NN of 23.47 g-3, and a 2021 reading of 16.38 g-3.

The environmental pollution caused by cemeteries and cremations: A review.

In recent years the funeral industry has drawn attention from the scientific community concerning the potential pollution of the environment and the urban environment. In this review, the pollution caused by the cemeteries and crematoria around the world was addressed. The traditional burial leads to the production of ions, in the form of organic and heavy metals, bacteria, fungi, and viruses, that spread along with the soil and underwater. The crematoria produce small particles, trace gases (SOx, NOx, CO), and toxic organic volatiles. The effluent generated by both methods can lead to several environmental problems and further threaten human health. The current solution for the cemeteries in the development of a system in which effluent generated by the traditional burials are collected and treated before realizing in the environment. In addition to that, the green burial should be an alternative, since the corpse does not go through the embalming process, thus eliminating the presence of any undesired chemicals, that are further leached onto the environment. The crematoria should be employed as it is, however, the gas treatment station should be employed, to ensure the minimization of the impact on the environment. Last, future researches regarding the treatment of the cemeteries leached still need to be explored as well as the optimization and further development of the crematoria gas treatment process.

Hazardous elements present in coal nanoparticles in a Caribbean port region in Colombia.

Scientific works examining coal-derived nanoparticles (NPs) containing potentially toxic elements (PTEs) confined in marine suspended sediments (MSSs) in port regions worldwide is an understudied topic, despite the fact that coal NPs have tremendous negative impacts on marine estuaries. The general objective of this study is to analyze the NP levels of coal, including PTEs, contained within MSSs in the general vicinity of the largest Caribbean port in Colombia. The morphology, size, chemical composition, and agglomeration states of NPs within MSSs of the sampled beaches were calculated through modern electron microscopy. The methodology used to detect chemical elements, unfortunately with EDS, it is not possible to precisely specify the chemical elements of low atomic weight (e.g. H, O, F, etc.) Therefore, with the EDS available today, it is only possible to have an idea of the chemical composition of each detected particle. Thus, it was possible to obtain the average frequency of the chemical elements identified in the 23 analyzed sampling points. Through the results, more than one thousand particles were detected in the most abundant phases, thus, the most frequent particles in the results of this manuscript were described. Sample point 8, located closest to the coal export port, had a higher concentration of nano-toxic elements (Al, Fe, Si, K, Mg, K) most concerning for human health in addition to being harmful to marine life. This study suggests that public policies dealing with MSS pollution need to be discussed by public managers to avoid further and sustained environmental degradation. The need to create projects will subsidize legacy liabilities generated by coal in seaports in other regions of the world.

Metals in the soil of urban cemeteries in Carazinho (South Brazil) in view of the increase in deaths from COVID-19: projects for cemeteries to mitigate environmental impacts.

The increasing mortality of COVID-19 can aggravate soil contamination by metals, harmful to the health of the population, requiring new projects for future cemeteries capable of mitigating these impacts to the environment, justifying the importance of studying the concentrations of metals in the soil of urban cemeteries. The paper analyzed the levels of metals in the soil of urban cemeteries in the City of Carazinho, in the state of Rio Grande do Sul, located in southern Brazil, considering the increase in deaths by COVID-19, for the purpose of future projects for cemeteries aimed at mitigating the impacts generated on the environment. The soils of the three urban cemeteries in Carazinho were sampled, with 5 internal and external points, with 3 repetitions at depths of 0-20 and 20-40 cm, adding 180 samples to measure the concentrations of Fe, Mn, Cu, Zn, Cr and Pb (g kg-1), considering the analytical sequence: (1) analysis in triplicate with mean deviation (RDS); (2) R2 of the analytical curve; (3) traceability of the pattern of each metal; (4) quantification limit of each metal (QL), with the performance of nitroperchloric digestion of the samples and the determinations of metals by flame modality atomic absorption spectrometry. Quantitative data on deaths by COVID-19 were analyzed by univariate modeling of time series, in the integrated autoregressive moving averages model. The results of this study were made available to fifteen architects, who attributed future solutions for environmentally sustainable cemeteries. The results showed high levels of copper (Cu) and iron (Fe) in the soil of the cemeteries studied. Considering the increase in deaths and subsequent burials per COVID-19 revealed a prediction for the death toll of 6,082,306 for June 9, 2022, it is assumed that metal contamination can reach even higher levels. To mitigate these levels of contamination by metals, 80% of the architect respondents expressed their preference for a vertical cemetery, with treatment of gases and effluents to mitigate environmental impacts.

Use of geospatial tools to predict the risk of contamination by SARS-CoV-2 in urban cemeteries.

Urban cemeteries are increasingly surrounded by areas of high residential density as urbanization continues world-wide. With increasing rates of mortality caused by the novel coronavirus, SARS-CoV-2, urban vertical cemeteries are experiencing interments at an unprecedented rate. Corpses interred in the 3rd to 5th layer of vertical urban cemeteries have the potential to contaminate large adjacent regions. The general objective of this manuscript is to analyze the reflectance of altimetry, normalized difference vegetation index (NDVI) and land surface temperature (LST) in the urban cemeteries and neighbouring areas of the City of Passo Fundo, Rio Grande do Sul, Brazil. It is assumed that the population residing in the vicinity of these cemeteries may be exposed to SARS-CoV-2 contamination through the displacement of microparticles carried by the wind as a corpse is placed in the burial niche or during the first several days of subsequent fluid and gas release through the process of decomposition. The reflectance analyses were performed utilizing Landsat 8 satellite images applied to altimetry, NDVI and LST, for hypothetical examination of possible displacement, transport and subsequent deposition of the SARS-CoV-2 virus. The results showed that two cemeteries within the city, cemeteries A and B could potentially transport SARS-CoV-2 of nanometric structure to neighboring residential areas through wind action. These two cemeteries are located at high relative altitudes in more densely populated regions of the city. The NDVI, which has been shown to control the proliferation of contaminants, proved to be insufficient in these areas, contributing to high LST values. Based on the results of this study, the formation and implementation of public policies that monitor urban cemeteries is suggested in areas that utilize vertical urban cemeteries in order to reduce the further spread of the SARS-CoV-2 virus.

Geo-environmental parametric 3D models of SARS-CoV-2 virus circulation in hospital ventilation systems.

The novel coronavirus, SARS-CoV-2, has the potential to cause natural ventilation systems in hospital environments to be rendered inadequate, not only for workers but also for people who transit through these environments even for a limited duration. Studies in of the fields of geosciences and engineering, when combined with appropriate technologies, allow for the possibility of reducing the impacts of the SARS-CoV-2 virus in the environment, including those of hospitals which are critical centers for healthcare. In this work, we build parametric 3D models to assess the possible circulation of the SARS-CoV-2 virus in the natural ventilation system of a hospital built to care infected patients during the COVID-19 pandemic. Building Information Modeling (BIM) was performed, generating 3D models of hospital environments utilizing Revit software for Autodesk CFD 2021. The evaluation considered dimensional analyses of 0°, 45°, 90° and 180°. The analysis of natural ventilation patterns on both internal and external surfaces and the distribution of windows in relation to the displacement dynamics of the SARS-CoV-2 virus through the air were considered. The results showed that in the external area of the hospital, the wind speed reached velocities up to 2.1 m/s when entering the building through open windows. In contact with the furniture, this value decreased to 0.78 m/s. In some internal isolation wards that house patients with COVID-19, areas that should be equipped with negative room pressure, air velocity was null. Our study provides insights into the possibility of SARS-CoV-2 contamination in internal hospital environments as well as external areas surrounding hospitals, both of which encounter high pedestrian traffic in cities worldwide.

Biophysical matter in a marine estuary identified by the Sentinel-3B OLCI satellite and the presence of terrestrial iron (Fe) nanoparticles.

The analysis of marine matter using the Sentinel-3B OLCI (Ocean Land Color Instrument) satellite is the most advanced technique for evaluating: the absorption of colored detrital and dissolved material (ADG_443_NN), total suspended matter concentration (TSM_NN) and of chlorophyll-a (CHL_NN) on a global scale. The objective is to analyze ADG_443_NN, TSM_NN and CHL_NN using the Sentinel-3B OLCI satellite and the presence of Fe-nanoparticles (NPs) + hazardous elements (HEs) in suspended sediments (SSs) in the maritime estuary of the Colombian city of Barranquilla. The study used the unpublished image of the Sentinel-3B OLCI satellite in the evaluation of ADG_443_NN, TSM_NN and CHL_NN in 72 sampled points. Subsequently, 36 samples of SSs were carried out in the Magdalena River, in the identification of Fe-NPs by advanced electron microscopies. The Sentinel-3B satellite revealed particulate accumulations in OCE1 through the intensity of OLCI in ocean. There was also a high Fe-NPs intensity of SSs in the Magdalena channel, spreading contamination to large regions.

Nanoparticles as vectors of other contaminants in estuarine suspended sediments: Natural and real conditions.

Studding the behaviour and danger of nanoparticles (NPs, minerals and amorphous phases) in the estuarine ecosystem is presently incomplete by the lack of measureable description of NPs in the ecological conditions, such as suspended-sediments (SS). In the last years, several works have revealed the toxic consequences of ultra-fine and nanoparticulate compounds on diverse systems, raising apprehensions over the nanocontaminants behaviour and destiny in the numerous ecological partitions. The general objective of the manuscript is to explain the geochemical conditions of the LES (Laguna estuarine system, southern Brazil) suspended sediments covering an area around the main South American coal plant, enhancing the creation of future public policies for environmental recovery projects. Subsequently the discharge of nanoparticles and toxic element (TE) in the ecosystem, NPs react with several constituents of the nature and suffers active alteration progressions. Contamination coming from engineering actions, wastewater, are something identifiable, however when these contaminations are accompanied by other contamination sources (e.g. mining and farming) the work gets defaulted. By combining material about the concentration of TE contaminants and NPs occurrences, this work offers novel visions into contaminant contact and the possible effects of such exposure on estuarine systems in Brazil. The results presented here will be useful for different areas of estuaries around the world.

Identification of hazardous nanoparticles present in the Caribbean Sea for the allocation of future preservation projects.

The deposition of remaining nanoparticles in the Caribbean Sea generates the formation of potentially dangerous elements, which influence at the imbalance of ecosystems. The detection of nanoparticles is not simple and the use of conventional methods is difficult application, which is why we highlight the immediacy and importance of this research for the areas of marine biology, urbanism, engineering and geosciences, applied in the Caribbean Sea. The general objective of this study is to evaluate the use of advanced methods for the determination of toxic nanoparticles, which can directly affect the development of marine organisms in the aquatic ecosystem in waters of the Caribbean Sea, favoring the construction of future international public policies with the elaboration of projects capable of mitigating these levels of contamination. The morphology and structure of nanoparticles were analyzed by emission scanning electron microscope with a high-resolution electron microscope. The nanoparticles smaller than 97 nm were identified in different proportions. The morphological analyses indicated nanoparticles' presence in the form of nanotubes, nanospheres, and nanofibers, which were shown in an agglomerated form. The presence of potentially hazardous elements, such as As, Cd, Pb, Mg, Ni and V were verified. In addition, the presence of asbestos in the form of minerals was confirmed, and that of titanium dioxide was found in large quantities. The results provide new data and emphasize the possible consequences to the in the Caribbean Sea, with the identification of dangerous elements (As, Cb, Pb, Hg, Ni and V), harmful to the marine ecosystem. Therefore, there is a need for strict control to reduce contamination of the Caribbean Sea and avoid risks to the ecosystem and public health, through suggestions of international public policies, through constant monitoring and the application of environmental recovery projects in this marine estuary.

Air pollutants and their degradation of a historic building in the largest metropolitan area in Latin America.

Historic buildings that comprise the cultural heritage of humanity are in need of preservation on a worldwide scale in regard to degradation resultant from atmospheric pollutants. The Brazilian Public Market, located in the historic center of the mega city of São Paulo, is the object of this research, due to its representation of historical Brazilian architecture. The general objective of this manuscript is to analyze the influence of air pollutants on the degradation of the historic São Paulo Public Market in the city of São Paulo, Brazil. Methodologically, between May 2018 and April 2019, samples of sedimented dust were collected at five points on the side walls of the market's historic structure, for the analysis of accumulated ultrafine particles (UFPs) and nanoparticles (NPs). A total of 20 samples of particulate matter were collected using self-made passive samplers (SMPSs). Using SMPSs, 12 months of accumulation and deposition were used to sample the atmospheric PM1. The results demonstrate the presence of dangerous elements such as: As, Cd, Cr, Pb, Zn. Note that EDS coupled with microscopy techniques, points out the risks to human health, due to the presence of these dangerous elements that accumulate in the building's structure. The results show that 85% of the NPs sampled contained Pb, and 56% contained Pb and Ti, which are harmful to both historic buildings and human health. Air pollution enables the further deterioration of the São Paulo Public Market, which is in need of restoration.

Hazardous elements in the soil of urban cemeteries; constructive solutions aimed at sustainability.

Urban cemeteries on a global scale raise concerns due to their potential to concentrate differing levels of hazardous pollutants in their native soils due to the unnatural concentration of burials in a limited space. It is paramount for sustainability that designers of future cemeteries take this into account in order to minimize the deposition and movement of these contaminants within the soil profile. The objective of this manuscript is to identify the levels of certain hazardous element contamination, specifically heavy metals, in the soil of horizontal urban cemeteries that do not utilize herbicides for weed control. In this, solutions were sought for the construction of future urban cemeteries capable of mitigating further contamination of the environment by the increase in interments. The soils of three urban cemeteries (A, B and C) in the Brazilian city of Carazinho, in Rio Grande do Sul State, were sampled with 5 monitoring points in the internal area and 5 points in the external area of the cemeteries. At each point, 3 replications were performed at two depths (0-20 and 20-40 cm), totaling 180 samples in all, to determine the concentration of the following metals: copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), lead (Pb), and chromium (Cr) (g kg-1). In addition, online interviews with 15 architects who design cemeteries were conducted. Architectural design solutions to mitigate environmental contamination were modeled utilizing the Building Information Modeling system (BIM). The results showed an excess of Cu in the soil of cemeteries A, B and C, surpassing the standards allowed by Brazilian federal regulations. A total of 80% of the interviewed architects expressed their preference for the vertical cemetery, with gas and effluent treatment systems to mitigate environmental impacts.

Environmental aspects of the depreciation of the culturally significant Wall of Cartagena de Indias - Colombia.

Among the diverse archeological relics of the past, the Cartagena de Indias Wall is one of the greatest representations of European cultural architecture in South America. To assess the implication of contamination on the depreciation of the culturally significant Wall of Cartagena de Indias - Colombia, a detailed, multi-analytical approach was conducted on components of the wall. Accumulated ultra-fine particles (UFPs) and superficial nano-particles (NPs) containing hazardous elements (HEs) on the wall were identified in an attempt to understand whether atmospheric pollution is hastening the depreciation of the structure itself. Mortar which at one point held the stones together is now weak and has fallen away in places. Irreparable damage is being done by salt spray, acid rain and the site's tropical humid climate. Several HEs and organic compounds found within the local environment are also contributing to the gradual deterioration of the construction. In this study, advanced microscopy analyses have been applied to understand the properties of UFPs and NPs deposited onto the wall's weathered external walls through exposure to atmospheric pollution. Several materials identified by X-Ray Diffraction (XRD) can be detected using high-resolution transmission electron microscopy (HR-TEM) and field emission scanning electron microscope (FE-SEM). The presence of anglesite, gypsum, hematite containing HEs, and several organic compounds modified due to moisture and contamination was found. Black crusts located on the structure could potentially serve as a source of HEs pollution and a probable hazard to not only to the ecosystem but also to human health.

Atmospheric nanocompounds on Lanzarote Island: Vehicular exhaust and igneous geologic formation interactions.

Atmosphere contamination management is one of the most important features in pollution risk management. The worldwide rise in tourism increases apprehension about its probable destructive conservation influence on various aspects of global conservation. One of the principal dangers increased by tourism-based modes of travel are nanoparticles (NPs) containing potentially hazardous elements (PHEs) contamination. One example of this is island destination of Lanzarote, in Spain's Canary Islands in which we examined contamination of the local atmosphere, water and soil. Important NPs containing PHEs, (e.g. arsenic, chromium, lead, and mercury), were found in this locale. It is reasonable to assume that this pollution poses an increased environmental danger to the local biome(s). Modes of transport (i.e. by car, airplane, bus) were shown to be an important contributor to this localized contamination as demonstrated by particulate matter (PM) readings collected near the island's airport. If no measures are taken to reduce vehicle and aircraft traffic, the tendency is to increase environmental degradation will continue unabated. As this particular area of Lanzarote is also one of wine production, increased pollution has the potential for negative impacts on the region's economy.

The impact of air pollution on the rate of degradation of the fortress of Florianópolis Island, Brazil.

The study of the prevalence of agglomerated nanoparticles (ANPs) containing potentially hazardous elements (PHEs) in the atmosphere is an emerging field of research. As such, the development of effective analytical procedures for the documentation of ANPs in air dust is vital for the evaluation of human health consequences. X-ray powder diffraction (XRD), Raman spectroscopy (RS), Mossbauer spectroscopy (MS) and advanced microscopy (AM) analyses of levels of pollutant concentration have been completed for many years in buildings worldwide. The chemical and mineralogical features of the Fortress of Nossa Senhora da Conceição de Araçatuba in the Brazilian state of Santa Catarina were utilized to catalog the geologic makeup of the structure's raw materials. Analyses of diverse categories of historical building were developed and performed to show the incidence of normal and anthropogenic compounds with PHEs. These geochemical effects and the subsequent fate and transport of nanoparticulate and colloidal (1-1000 nm) compounds in the atmosphere have remained a focus of study for many years. However, the data published in the scientific literature is nowhere near adequate to generate an exhaustive standard of the performance, fate, and transport of natural and anthropogenic ANPs in the atmosphere. Studies to date do provide a preliminary argument for the human health risk calculations from historical buildings due to ANPs. Thus, the geochemical makeup of ANPs and their position in collected nanomineral-organic accumulations may offer some insight into their source. Our ability to detect such ANPs may decrease over time due to the tendency of historical buildings to accrete sludge over the years. The occurrence of PHEs in atmospheric ANPs has not formerly been recognized on the island environment examined in this study. However, it has been shown that it presents a clear and present danger to the preservation of historical monuments.